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CHEM-TOX PERMATOX INSECTICIDE
EPA Registration No. 45385-69 • Product Code: EC-533
ACTIVE INGREDIENT CHEMICAL NAME: Mixture; Active Ingredient, Permethrin
CHEMICAL FAMILY: Synthetic Pyrethroid
HMIS Rating: Health: 2
Flammability: 1t
Reactivity: 1
Protection: Safety Glasses & Rubber Gloves
Manufacturer's Name:
CTX/Cenol, Inc.
Address: P.O. Box 472
Twinsburg, Ohio 44087


Prepared by: Bart Baker
Emergency Telephone Number:
CHEMTREC at 1-800-424-9300 or
National Pesticide Telecommunications Network at 1-800-858-7378 or Telephone Number for Information:
9 AM to 5 PM EST - 888-281-7025

Date Prepared: April 08, 2002
HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
OSHA LIMITS
HAZARDOUS COMPONENTS


ACTIVE INGREDIENTS:
Permethrin: ((3-Phenoxyphenyl)methyl(±)-
cis,trans-3-(2,2-dichloroethynyl)-2-2-dimethyl-
cyclopropanecarboxylate)

**INACTIVE INGREDIENTS:
Aromatic Petroleum Solvents **A proprietary mixture of solvent and surfactants

This product contains a toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III and of 40 CFR 372. Any copies or redistribution of this MSDS must include this notice.
CAS NUMBER





52645-53-1



--
STEL




N/A



N/A
CEILING




N/A



N/A
ACGIH TLV0




N/A



N/A
PEL




N/A



100 ppm
% (optiona)



13.0



87.0
PHYSICAL / CHEMICAL CHARACTERISTICS
BOILING POINT: (F): >176° F or 80° C

SOLUBILITY IN H2O: Miscible / Dispersible

APPEARANCE / ODOR: Clear brown liquid. Solvent odor.

MELTING POINT: N/A

EVAPORATION RATE (BUTYL ACETATE = 1): N/A
SPECIFIC GRAVITY: (Water = 1): 0.91 - 0.93

VAPOR PRESSURE: (mm hg): (mm hg): 15 mmHg @ 25° C

VAPOR DENSITY: Below 1

pH: Neutral 5.4 (8% in water)
FIRE AND EXPLOSION HAZARD INFORMATION
FLASH POINT: >151°-154° F / >66°-68° C METHOD USED: TCC
Flammable Limits - LEL: N/A UEL: N/A STP: 1.1 -7.0 (Xylene)
EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or CO2.
SPECIAL FIRE FIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure demand, MSHA/NIOSH approved (or equivalent) and full protective gear. Keep out of smoke, cool exposed containers with water spray, prevent spread of contaminated runoff.
UNUSUAL FIRE & EXPLOSION HAZARDS:Keep containers cool, combustible liquid. Avoid explosive ignition. May give of Hydrogen Chloride gas upon combustion or at high temperatures
REACTIVITY DATA
CHEMICAL STABILITY: Stable.
CONDITIONS TO AVOID: Avoid extreme heat or source of ignition.
INCOMPATIBLE MATERIALS: Avoid strong oxidizing agents.

HAZARDOUS POLYMERIZATION: Will not occur
CONDITIONS TO AVOID FOR HAZARDOUS
POLYMERIZATION: None

HAZARDOUS DECOMPOSITION: Carbon dioxide, carbon monoxide oxide, sulfur oxides, halogen, halogen acids, possible trace amounts of carbonyl halide.
HEALTH HAZARD DATA
Route(s) of Entry: Inhalation? - YES Skin? - YES Ingestion? - YES
HEALTH HAZARDS (ACUTE and CHRONIC): Acute exposure may lead to irritation of eyes and mucosa and nervous system symptoms. May cause allergic reaction in sensitive individuals.
Carcinogenicity: NTP? - No IARC Monographs? - No OSHA Regulated? No
SIGNS & SYMPTOMS OF EXPOSURE: May cause eye irritation on contact. Harmful if swallowed.

WORK/HYGIENIC PRACTICES: Wash thoroughly after handling and before smoking or eating.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Eye, skin and respiratory disorders.
FIRST AID PROCEDURES:
EYES:
Flush with plenty of water. Get prompt medical attention.
SKIN: Wash thoroughly with plenty of soap and water.
INHALATION: Remove individual to fresh air. Get medical attention if breathing difficulty develops.
INGESTION: Do NOT induce vomiting. Call a physician immediately.
PRECAUTIONS FOR SAFE HANDLING AND DISPOSAL
IN CASE MATERIAL IS RELEASED OR SPILLED: Soak up spill in absorbent material. Hold for disposal. Do not contaminate any water resource. Product is highly toxic to fish.
WASTE DISPOSAL METHOD: Dispose of in accordance with Federal, State and Local Waste Disposal Rules.
HANDLING PRECAUTIONS: Avoid unnecessary contact with material. Wash up after handling or use. Wash contaminated clothing before reuse.
CONTROL MEASURES
RESPIRATORY PROTECTION:Use a respirator, such as the Wilson 6000 Series, with an organic vapor cartridge and pesticide prefilter.

VENTILATION: Use product in well ventilated areas.

LOCAL EXHAUST: N/A SPECIAL EXHAUST: N/A

MECHANICAL EXHAUST: Fans as necessary.

OTHER EXHAUST: N/A

PROTECTIVE GLOVES: Chemical resistant.
EYE PROTECTION: Safety glasses, goggles or face shield..

SKIN PROTECTION: Chemically impervious gloves
and apron.

GENERAL PROTECTION: Eye wash facility and safety shower should be available.

WORK / HYGIENIC PRACTICES: Avoid eye and skin contact. Wash thoroughly after handling and before eating.
SARA TITLE III SECTION 311/312 • HAZARD CLASSES
SARA Title III (Superfund Amendments & Reauthorization Act)

Section 302 (40 CFR 355) (EHS) Ingredients: Not listed.

Section 311 (40 CFR 370)

Section 312 (40 CFR 370) Threshold Planning Quantity (TPQ). The TPQ for this product, if treated as a mixture in 10,000 lbs. This product contains the following ingredient with a TPQ of less than 10,000 lbs.: None
Section 313 (40- CFR 372) Reportable Ingredients: This product contains the following ingredients subject to
section 313 Reportable Ingredients: Permethrin.

CERCLA REGULATORY (40 CFR 302.4): Not listed.
REGULATORY INFORMATION
TSCA (Toxic Substances Control Act) Regulations, 40 CFR 710: This
product is a pesticide and is exempt from TSCA regulation.
U.S. EPA Signal Word: CAUTION